Cloud computing has largely passed through it's hype phase - that period where all kinds of magical characteristics are applied to it because no one really knows that much about it, and is shifting to the real world scenarios where people are actually building clouds and finding the limitations therein (and the cycle goes through the Trough of Despair).
Despite this incipient skeptical phase, there are some significant reasons to think hard about the combination of cloud computing and XML Databases, especially those such as MarkLogic or eXist-db that combine the database with a web app server. There are many ways of using such servers, though I believe one of the most powerful is to use a RESTful Services approach in conjunction with URL rewriting in order to create intelligent file systems.